Carbon cycle modelling and the residence time of natural,  anthropogenic atmospheric CO2

Carbon cycle modelling and
the residence time of natural and
anthropogenic atmospheric CO2:
on the construction of the
"Greenhouse Effect Global Warming" dogma.

Tom V. Segalstad

Mineralogical-Geological Museum
University of Oslo
Sars' Gate 1, N-0562 Oslo
Norway

When you have eliminated the impossible,
whatever remains, however improbable, must be the truth.

Sir Arthur Conan Doyle (1859-1930).

Abstract

The three evidences of the United Nations Intergovernmental Panel on Climate Change (IPCC), that the apparent contemporary atmospheric CO2 increase is anthropogenic, is discussed and rejected: CO2 measurements from ice cores; CO2 measurements in air; and carbon isotope data in conjunction with carbon cycle modelling.

It is shown why the ice core method and its results must be rejected; and that current air CO2 measurements are not validated and their results subjectively "edited". Further it is shown that carbon cycle modelling based on non-equilibrium models, remote from observed reality and chemical laws, made to fit non-representative data through the use of non-linear ocean evasion "buffer" correction factors constructed from a pre-conceived idea, constitute a circular argument and with no scientific validity.

Both radioactive and stable carbon isotopes show that the real atmospheric CO2 residence time (lifetime) is only about 5 years, and that the amount of fossil-fuel CO2 in the atmosphere is maximum 4%. Any CO2 level rise beyond this can only come from a much larger, but natural, carbon reservoir with much higher 13-C/12-C isotope ratio than that of the fossil fuel pool, namely from the ocean, and/or the lithosphere, and/or the Earth's interior.

The apparent annual atmospheric CO2 level increase, postulated to be anthropogenic, would constitute only some 0.2% of the total annual amount of CO2 exchanged naturally between the atmosphere and the ocean plus other natural sources and sinks. It is more probable that such a small ripple in the annual natural flow of CO2 would be caused by natural fluctuations of geophysical processes.

13-C/12-C isotope mass balance calculations show that IPCC's atmospheric residence time of 50-200 years make the atmosphere too light (50% of its current CO2 mass) to fit its measured 13-C/12-C isotope ratio. This proves why IPCC's wrong model creates its artificial 50% "missing sink". IPCC's 50% inexplicable "missing sink" of about 3 giga-tonnes carbon annually should have led all governments to reject IPCC's model. When such rejection has not yet occurred, it beautifully shows the result of the "scare-them-to-death" influence principle.

IPCC's "Greenhouse Effect Global Warming" dogma rests on invalid presumptions and a rejectable non-realistic carbon cycle modelling which simply refutes reality, like the existence of carbonated beer or soda "pop" as we know it.

1. Introduction

The atmospheric CO2 is as important as oxygen for life on Earth. Without CO2 the plant photosynthetic metabolism would not be possible, and the present life-forms on Earth would vanish. Over the last years it has been constructed a dogma that an apparent increase in atmospheric CO2 concentration is caused by anthropogenic burning of fossil carbon in the forms of petroleum, coal, and natural gas. This extra atmospheric CO2 has been claimed to cause global climatic change with a significant atmospheric temperature rise of 1.5 to 4.5°C in the next decennium (Houghton et al., 1990).

There is then indeed a paradox that CO2, "The Gas of Life", is now being condemned as the evil "polluting" gas, a gas which will be a threat to people's living on Earth, through a postulated "Global Warming". Even more so when earlier warmer periods in the Earth's history have been characterized as "Climatic Optimum". The construction of the "CO2 Greenhouse Effect Doom" dogma, based on atmospheric CO2 level measurements in air and ice cores, carbon cycle modelling, CO2 residence time (lifetime is here used synonymously), and carbon isotopes, is here examined, and the dogma is rejected on geochemical grounds.

2. The construction of dogmas

In natural sciences the scientific method is based on the testing of hypotheses with the help of (1) empiric observations, (2) laboratory experiments, and (3) theory based on these. If these three parts give identical results, and the theory also is so robust that it will predict future results which will be identical to new observations and experiments, we have found a hypothesis with high significance. With further testing this hypothesis can be exalted to a law of nature, which in turn can be used to reject other hypotheses not supported by observations and experiments. It is of course fundamental that all three major parts of the scientific method is based on sound statistical procedures regarding sampling theory, data representation, significance, error propagation, causality, etc., and should be unbiased and free of advocacy. If any parts of the evidence does not support the hypothesis, the hypothesis should be rejected (Churchman, 1948).

Over the last years, mainly after the fall of the communism, environmentalism seems to have taken the vacant place on the political scene. This new "ism" alleges that Man is destructive, unnatural, evil, and guilty of destructing the environment on this planet. The "proofs" used in this respect are based on selected portions of science, in many cases not based on the objectivity of the scientific method of natural sciences (Sanford, 1992).

Rather the "proofs" concert rejection of reason, and are based on the scientific method of philosophy, where the fundamental 3 parts of the scientific method of natural sciences do not apply. In natural sciences knowledge is obtained by validating the content of one's mind according to the facts of reality. Truth then corresponds to reality. In philosophy the world is artificial, and truth is redefined to mean coherence among ideas, along the views of the philosopher Immanuel Kant. Hence a dogma can be constructed by ignoring reality, and rather appealing to authority or consensus as invalid substitutes for reason. In philosophy hypotheses can be proposed, validated, and accepted without reference to facts (Sanford, 1992). We see that most often the treatment of what is normal or natural is lacking from the environmental "dooms", and that we only are told what is "abnormal" or "unnatural" without an indisputable baseline reference.

To construct a dogma the methodology is to start with an idea one feels correct and then finding evidence to support it. Reason will then have to be substituted by intuition, belief, faith, emotions, or feelings as the ultimate source of knowledge. Sanford (1992) further points out that the "ecosopher" Arne Næss (1990) begins a book with the section "Beginning with intuitions" and a feeling of "our world in crisis". The dogma will be accepted as truth by the people at large if it will be supported by "authorities", "experts", and well-known important people, not necessarily with their expertise in the relevant field; and especially so if the dogma is being supported by international bodies or assemblies, and given a wide and one-sided coverage by the media. The dogma will be even more appealing if it appears as a self-fulfilling prophecy.

The marketing and influence, i.e. the psychology of persuasion of a dogma, will therefore be important for it to be accepted as truth. The greater the number of people who find any idea correct, the more the idea will appear to be correct among people. People are usually not able to use all relevant information available. They use instead only a single, highly representative piece of the relevant information. When something is presented as a scary scenario, it creates an emotional reaction that makes it difficult to think straight (i.e. consider all facts), especially if there has been created a belief that decisions regarding a common crisis will have to be made fast (Cialdini, 1993). This is what has been called the "scare-them-to-death" approach (Böttcher, 1996), and makes the foundation for creating a doomsday dogma. Stephen Schneider, a climatologist and leading proponent of the global warming theory, says: "To capture the public imagination ... we have to offer up some scary scenarios, make simplified dramatic statements and little mention of any doubts one might have", thereby acting as an advocate for his subjective belief in the "Greenhouse Effect Global Warming" dogma rather than as an objective scientist (Sanford, 1992).

A doomsday dogma made under these conditions will very likely cause a political turmoil. The old saying "Everybody talks about the weather, and nobody does anything about it" is claimed to be invalid when Man's burning of fossil fuel allegedly will change the world's climates. The creation of a "CO2 Greenhouse Effect Doom" dogma will easily give more power and money to politicians and people at power, letting them introduce legislation and taxation on energy consumption and people's way of living by implementing policies infringing on people's technology, industry, and freedom.

3. The foundation of the CO2 dogma - early atmospheric CO2 measurements

In order to construct a "CO2 Greenhouse Effect Doom" dogma, it will be necessary to justify that (1) pre-industrial atmospheric CO2 was lower than today, (2) atmospheric CO2 has steadily risen from its pre-industrial level to today's level, (3) Man's burning of fossil fuel is causing an increase in atmospheric CO2 level, (4) hence atmospheric CO2 must have a long residence time (lifetime), and (5) atmospheric temperatures are increasing due to Man's burning of fossil fuel.

Callendar (1938) revived the hypothesis of "Greenhouse Warming" due to Man's activity, proposed by Arrhenius (1896). Callendar may truly be regarded as the father of the current dogma on man-induced global warming (Jaworowski et al., 1992 b). In order to support his hypothesis, Callendar (1940, 1958) selected atmospheric CO2 data from the 19th and 20th centuries. Fonselius et al. (1956) showed that the raw data ranged randomly between about 250 and 550 ppmv (parts per million by volume) during this time period, but by selecting the data carefully Callendar was able to present a steadily rising trend from about 290 ppmv for the period 1866 - 1900, to 325 ppmv in 1956.

Callendar was strongly criticized by Slocum (1955), who pointed out a strong bias in Callendar's data selection method. Slocum pointed out that it was statistically impossible to find a trend in the raw data set, and that the total data set showed a constant average of about 335 ppmv over this period from the 19th to the 20th century. Bray (1959) also criticized the selection method of Callendar, who rejected values 10% or more different from the "general average", and even more so when Callendar's "general average" was neither defined nor given.

Note that Callendar (1940) wrote: "There is, of course, no danger that the amount of CO2 in the air will become uncomfortably large because as soon as the excess pressure in the air becomes appreciable, say about 0.0003 atmos., the sea will be able to absorb this gas as fast as it is likely to be produced."

Callendar (1949) repeated this fact, but went on to say: "As the deep waters of the sea move slowly and only shallow contact surface is involved in the carbon-dioxide equilibrium, this reservoir does not immediately control a sudden eruption of the gas such as has occurred this century. It will be hundreds or perhaps thousands of years before the sea absorbs its fair share." Callendar believed that nearly all the CO2 produced by fossil fuel combustion has remained in the atmosphere. He suggested that the increase in atmospheric CO2 may account for the observed slight rise in average temperature in northern latitudes during the recent decades.

The "CO2 Greenhouse Effect Doom" was being substantiated by Revelle & Suess (1957) who wrote: "Thus human beings are now carrying out a large scale geophysical experiment of a kind which could not have happened in the past nor be reproduced in the future. Within a few centuries we are returning to the air and oceans the concentrated organic carbon stored over hundreds of millions of years." But by considering the chemical facts on the exchange of CO2 between the atmosphere and the ocean, they concluded that only a total increase of 20 to 40% in atmospheric CO2 can be anticipated by burning all fossil fuel. This is comparable to the 20% increase calculated by Segalstad from the air/sea CO2 partition coefficient given by chemical equilibrium constants (Segalstad, 1996).

At the same time Craig (1957) pointed out from the natural (by cosmic rays) radiocarbon (14-C) production rate that atmospheric CO2 is in active exchange with very large CO2 reservoirs in the ocean and biosphere. However, Callendar (1958) had apparently more faith in his carefully selected CO2 data, because he commented Craig's conclusion by writing: "Thus, if the increase shown by the measurements discussed here is even approximately representative of the whole atmosphere, it means that the oceans have not been accepting additional CO2 on anything like the expected scale."

4. The building of the dogma - recent atmospheric CO2 measurements

The stir around the atmospheric CO2 data selected by Callendar made it necessary to start compiling analytical data of contemporary atmospheric CO2. 19 North-European stations measured atmospheric CO2 over a 5 year period from 1955 to 1959. Measuring with a wet-chemical technique the atmospheric CO2 level was found to vary between approximately 270 and 380 ppmv, with annual means of 315 - 331 ppmv, and there was no tendency of rising or falling atmospheric CO2 level at any of the 19 stations during this 5 year period (Bischof, 1960). The data are particularly important because they are unselected and therefore free of potential biases from selection procedures, unlike the CO2 measurements based on the procedures at Mauna Loa (see below). Note that these measurements were taken in an industrial region, and would indeed have shown an increase in CO2 levels if increasing amounts of anthropogenic CO2 were accumulating in the atmosphere during this period.

During the same period atmospheric CO2 measurements were started near the top of the strongly CO2-emitting (e.g., Ryan, 1995) Hawaiian Mauna Loa volcano. The reason for the choice of location was that it should be far away from CO2-emitting industrial areas. At the Mauna Loa Observatory the measurements were taken with a new infra-red (IR) absorbing instrumental method, never validated versus the accurate wet chemical techniques. Critique has also been directed to the analytical methodology and sampling error problems (Jaworowski et al., 1992 a; and Segalstad, 1996, for further references), and the fact that the results of the measurements were "edited" (Bacastow et al., 1985); large portions of raw data were rejected, leaving just a small fraction of the raw data subjected to averaging techniques (Pales & Keeling, 1965).

The acknowledgement in the paper by Pales & Keeling (1965) describes how the Mauna Loa CO2 monitoring program started: "The Scripps program to monitor CO2 in the atmosphere and oceans was conceived and initiated by Dr. Roger Revelle who was director of the Scripps Institution of Oceanography while the present work was in progress. Revelle foresaw the geochemical implications of the rise in atmospheric CO2 resulting from fossil fuel combustion, and he sought means to ensure that this 'large scale geophysical experiment', as he termed it, would be adequately documented as it occurred. During all stages of the present work Revelle was mentor, consultant, antagonist. He shared with us his broad knowledge of earth science and appreciation for the oceans and atmosphere as they really exist, and he inspired us to keep in sight the objectives which he had originally persuaded us to accept." Is this the description of true, unbiased research?

The annual mean CO2 level as reported from Mauna Loa for 1959 was 315.83 ppmv (15 ppmv lower than the contemporaneous North-European average level), reportedly rising steadily to 351.45 in January 1989 (Keeling et al., 1989), by averaging large daily and seasonal variations (the significance of all their digits not justified), but still within the range of the North European measurements 30-35 years earlier. Hence a rise in global atmospheric CO2 level has not yet been significantly justified by validated methods and sound statistics.

5. Setting the dogma baseline - CO2 measurements in ice cores

In order to show that recent atmospheric CO2 levels have risen due to Man's burning of fossil fuel, it was necessary to show a significant level increase above pre-industrial CO2 levels. We saw how Callendar was able to set a baseline of about 290 ppmv by rejecting values deviating more than 10% from his desired value.

It was believed that snow accumulating on ice sheets would preserve the contemporaneous atmosphere trapped between snowflakes during snowfalls, so that the CO2 content of air inclusions in cores from ice sheets should reveal paleoatmospheric CO2 levels. Jaworowski et al. (1992 b) compiled all such CO2 data available, finding that CO2 levels ranged from 140 to 7,400 ppmv. However, such paleoatmospheric CO2 levels published after 1985 were never reported to be higher than 330 ppmv. Analyses reported in 1982 (Neftel at al., 1982) from the more than 2,000 m deep Byrd ice core (Antarctica), showing unsystematic values from about 190 to 420 ppmv, were falsely "filtered" when the alleged same data showed a rising trend from about 190 ppmv at 35,000 years ago to about 290 ppmv (Callendar's pre-industrial baseline) at 4,000 years ago when re-reported in 1988 (Neftel et al., 1988); shown by Jaworowski et al. (1992 b) in their Fig. 5.

Siegenthaler & Oeschger (1987) were going to make "model calculations that are based on the assumption that the atmospheric [CO2] increase is due to fossil CO2 input" and other human activities. For this modelling they constructed a composite diagram of CO2 level data from Mauna Loa and the Siple (Antarctica) core (see Jaworowski et al., 1992 b, Fig. 10). The data from the Siple core (Neftel et al., 1985) showed the "best" data in terms of a rising CO2 trend. Part of the reason for this was that the core partially melted across the Equator during transportation before it was analysed (Etheridge et al., 1988), but this was neither mentioned by the analysts nor the researchers later using the data (see Jaworowski et al., 1992 b). Rather it was characterized as "the excellent quality of the ice core" and its CO2 concentration data "are assumed to represent the global mean concentration history and used as input data to the model" (Siegenthaler & Oeschger, 1987). The two CO2 level curves were constructed to overlap each other, but they would not match at corresponding age.

In order to make a matching construction between the two age-different non-overlapping curves, it was necessary to make the assumption that the age of the gas inclusion air would have to be 95 years younger than the age of the enclosing ice. But this was not mentioned by the originators Siegenthaler & Oeschger (1987). This artificial construction has been used as a basis for numerous speculative models of changes in the global carbon cycle.

Carbon cycle modelling and CO2 - 2 - 3 - 4

http://folk.uio.no/tomvs/esef/ESEF3VO2.htm

In accordance with Title 17 U.S.C. Section 107, this material is distributed without profit to those who have expressed a prior interest in receiving the included information for research and educational purposes.